SBA-15-functionalized sulfonic acid confined acidic ionic liquid: a powerful and water-tolerant catalyst for solvent-free esterifications.
نویسندگان
چکیده
Incorporating a hydrophobic Brønsted acid ionic liquid (HBAIL) inside the nanospaces of SBA-15-Pr-SO(3)H led to a hydrophobic super Brønsted acid catalyst, which showed excellent catalytic performance in direct esterification of alcohols and carboxylic acids at ambient temperature under solvent-free conditions.
منابع مشابه
Magnetic Ionic Liquid Functionalized Sulfonic Acid: a Green and Efficient Catalyst for the One-pot Synthesis of 1-Amidoalkyl-2-Naphtols
In this study, a novel acidic magnetic dicationic ionic liquid was prepared in three steps to serve as a green catalyst in organic synthesis. The newly synthesized catalyst was characterized UV- VIS, and VSM analysis. Additionally, the decomposition steps acatalyst were investigated by thermal analysis techniques (TGA/DSC). The synthesized acidic magnetic dication...
متن کاملOne Pot Synthesis of Polyhydroquinolines Catalyzed by Sulfonic Acid Functionalized SBA-15 as a New Nanoporous Acid Catalyst under Solvent Free Conditions
Sulfonic acid functionalized SBA-15 (SBA-Pr-SO3H) as a new nanoporous acid catalyst was used in the one-pot synthesis of polyhydroquinolines derivatives via the Hantzsch four component condensation reaction of aldehydes, b-ketoesters, dimedone and ammonium acetate under solvent free conditions with short reaction time in excellent yields. SBA-P...
متن کاملBrønsted acidic ionic liquid as the efficient and reusable catalyst for synthesis of coumarins via Pechmann condensation under solvent-free conditions
A mild and efficient method has been developed for the preparation of substituted coumarins from reaction of various phenols with different β-ketoesters via Pechmann condensation in the presence of Brønsted acidic ionic liquid (N-(4-sulfonic acid) butyl triethylammonium hydrogen sulfate) as an effective catalyst under solvent-free conditions. Different phenols reacted with ethyl acetoacetate to...
متن کاملBrønsted acidic ionic liquid as the efficient and reusable catalyst for synthesis of coumarins via Pechmann condensation under solvent-free conditions
A mild and efficient method has been developed for the preparation of substituted coumarins from reaction of various phenols with different β-ketoesters via Pechmann condensation in the presence of Brønsted acidic ionic liquid (N-(4-sulfonic acid) butyl triethylammonium hydrogen sulfate) as an effective catalyst under solvent-free conditions. Different phenols reacted with ethyl acetoacetate to...
متن کاملBrønsted Acidic Phosphonium Based Ionic Liquid Functionalized SBA-15 [HO3S-PhospIL@SBA-15]: Green, Recyclable, and Efficient Catalyst for the Synthesis of Pyrano[3,2-c]Chromenone Derivatives
The surface of SBA-15 was modified by diphenylphosphine; then, it was treated with butane sultone and sulfuric acid to obtain Brønsted acid HO3S-phosphonium based ionic liquid functionalized SBA-15 with HSO4- as a counteranion. It efficiently catalyzed synthesis of pyrano[3,2-c]chromenone derivatives through the reaction of 4-hydroxycoumarin and chalcones at...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 48 27 شماره
صفحات -
تاریخ انتشار 2012